✦ LIBER ✦

Normal, abnormal and pseudo-abnormal reaction pathways for the imine-peroxyacid reaction

✍ Scribed by Derek R. Boyd; Peter B. Coulter; Narain D. Sharma; W.Brian Jennings; Valerie E. Wilson

Book ID: 104228734
Publisher: Elsevier Science
Year: 1985
Tongue: French
Weight: 216 KB
Volume: 26
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)98582-4

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✦ Synopsis

Steric and mesomeric effects have a marked influence upon the formation of oxaziridine (normal pathway) or nitrone (abnormal pathway) products from the imine-peroxyacid reaction; n.m.r. studies of the thermal isomerization of oxaziridines to nitrones provide evidence of a pseudo-abnormal oxidation pathway.

The imine-peroxyacid reaction generally provides a good synthetic route to oxaziridines. l-5

In view of the very wide range of N-alkyl oxaziridines which has been formed by this method, this reaction pathway (a) may be classified as 'normal'.

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