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Reactions of cyclic phosphorochloridous esters with dienic hydrocarbons

โœ Scribed by B. A. Arbuzov; L. A. Shapshinskaya; V. M. Erokhina


Book ID
112421399
Publisher
Springer
Year
1965
Tongue
English
Weight
356 KB
Volume
14
Category
Article
ISSN
1573-9171

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โœ William G. Dauben; William R. Baker ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 190 KB

The Diels-Alder reaction of e-benzoquinone with substituted dienoic esters affords good yields of 4a,5,8,8a-tetrahydro-1,4+aphthalenediones, free from the isomeric hydroquinone. The reactions were conducted at room temperature under 15 kbar (1.5 GPa) pressure in dichloromethane solutions.