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Reactions of cyanotrihydroborate ion and its derivatives with halogens

✍ Scribed by Donald R. Martin; Miguel A. Chiusano; Michael L. Denniston; D.James Dye; E.Dale Martin; B.Timothy Pennington

Book ID
115975261
Publisher
Elsevier Science
Year
1978
Weight
406 KB
Volume
40
Category
Article
ISSN
0022-1902

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The reaction of NH3 with CbFgS020CH2CF3 has been shown to yield, depending on the molar ratio, FgCCH2NH2, (F5CCH212NH and the novel tertiary amine IF5CCH213N (1111. Halogenation of (1111 with Br2 and Cl2 at the a-position formed (FgCCH212NCBrHCFg , FSCCH2NICBrHCFg12 and NICCIHCF515. Compound 11111 w