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Reactions of [Cp 2 MCl 2- 7 (M = Ti or Zr and Cp = η 5 -C 5 H 5 ) with Multidentate Ligands and the Synthesis of New Cyclopentadienyl Derivatives of Titanium and Zirconium

✍ Scribed by Dey, Kamalendu; Bandyopadhyay, Debasish; Nandi, Kartik K.; Poddar, Sailendra N.; Mukhopadhyay, Gurucharan; Kauffman, George B.


Book ID
126607850
Publisher
Taylor and Francis Group
Year
1992
Tongue
English
Weight
569 KB
Volume
22
Category
Article
ISSN
0094-5714

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✍ Paul-Michael Pellny; Vladimir V. Burlakov; Wolfgang Baumann; Anke Spannenberg; U 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 213 KB 👁 1 views

The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,