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Reactions of coordinated nucleophiles. Intramolecular imine formation

✍ Scribed by Harrowfield, J. MacB.; Sargeson, A. M.


Book ID
126273171
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
256 KB
Volume
96
Category
Article
ISSN
0002-7863

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AbstractÐ2-(ortho-Hydroxyphenyl)-alkynethiolates and -selenolates, obtained through base catalyzed ring cleavage of 4-(ortho-hydroxyphenyl)-1,2,3-thiadiazoles and -1,2,3-selenadiazoles, smoothly transform into 2-benzofuranthiolates and -selenolates. These reactive intermediates can be alkylated in h