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Nucleophilic Intramolecular Cyclization Reactions of Alkynechalcogenolates

✍ Scribed by M.A. Abramov; W. Dehaen; B. D'hooge; M.L. Petrov; S. Smeets; S. Toppet; M. Voets

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
137 KB
Volume
56
Category
Article
ISSN
0040-4020

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✦ Synopsis

AbstractÐ2-(ortho-Hydroxyphenyl)-alkynethiolates and -selenolates, obtained through base catalyzed ring cleavage of 4-(ortho-hydroxyphenyl)-1,2,3-thiadiazoles and -1,2,3-selenadiazoles, smoothly transform into 2-benzofuranthiolates and -selenolates. These reactive intermediates can be alkylated in high yield. This reaction sequence could be applied to the synthesis of electron rich thiacrown ethers. The 2-(ortho-aminophenyl)-alkynethiolate analogously forms 2-methylsulfanylindole.

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ChemInform Abstract: Nucleophilic Intram
ChemInform Abstract: Nucleophilic Intramolecular Cyclization Reactions of Alkynechalcogenolates.
✍ M. A. Abramov; W. Dehaen; B. D'hooge; M. L. Petrov; S. Smeets; S. Toppet; M. Voe πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

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