Reactions of cobalt(II) macrocycles with alkyl and alkylperoxy radicals
β Scribed by Bakac, Andreja; Espenson, James H.
- Book ID
- 125931874
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 528 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
Cross-disproportionation/combination ratios for CFH2 and CF3 with C2H5 radicals have been determined to be A = 0.032 f 0.012 and A = 0.098 f 0.020, respectively, over the temperature range 25-75Β°C. For the pathway that yields CFH and CzHs, A = 0.020 f 0.005 a t 25Β°C.
## Abstract The recombination reactions of prototypical alkyl radicals (R) with O~2~, R + O~2~ β RO~2~, have been investigated theoretically by using the variational transition state theory and RiceβRamspergerβKasselβMarcus theory/master equation calculations based on the CASPT2(7,5)/augβccβpVDZ//B