## Abstract Relative rate constants for the gasโphase reactions of OH radicals with a series of alkyl nitrates have been determined at 299 ยฑ 2 K, using methyl nitrite photolysis in air as a source of OH radicals. Using a rate constant for the reaction of OH radicals with cyclohexane of 7.57 ร 10^โ1
Gas phase oxidative-addition reactions of alkyl radicals at complexed cobalt(II) centres
โ Scribed by G.W. Dillow; I.K. Gregor; M. Guilhaus
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 503 KB
- Volume
- 294
- Category
- Article
- ISSN
- 0022-328X
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๐ SIMILAR VOLUMES
By photolyzing azomethane over the temperature range 331-491 K in the presence of trifluoroacetone the kinetics of the addition reaction (11, CH3 + CF3COCH3 + CF,C(O)(CH, )z have been studied. Detailed analyses have shown that the principal product of the adduct radical, CF3C(0)(CH3)2, is CH,COCH, f
Trifluoro-t-butoxy radicals have been generated by reacting fluorine with 2-trifluoromethyl propan-2-01: Over the temperature range 361-600 K the trifluoro-t-butoxy radical decomposes exclusively by loss of the -CF, group [reaction ( -2)] rather than by loss of -CH, group [reaction ( -111: The lim
## Abstract Rate constants for the reactions of OH radicals and Cl atoms with CH~3~ONO, C~2~H~5~ONO, __n__โC~3~H~7~ONO, __n__โC~4~H~9~ONO, and __n__โC~5~H~11~ONO have been determined at 298 ยฑ 2 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rat