Reactions of Cl Atoms with Selected VOCs: Kinetics, Products and Mechanisms
β Scribed by Gaia Fantechi; Niels R. Jensen; Ole Saastad; Jens Hjorth; Jozef Peeters
- Book ID
- 110231491
- Publisher
- Springer Netherlands
- Year
- 1998
- Tongue
- English
- Weight
- 177 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0167-7764
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## Abstract The rate coefficients for the reactions of Cl atoms with CH~3~Br, (__k__~1~) and CH~2~Br~2~, (__k__~2~) were measured as functions of temperature by generating Cl atoms via 308 nm laser photolysis of Cl~2~ and measuring their temporal profiles via resonance fluorescence detection. The m
The kinetics and mechanism of the reaction Cl Ο© HO 2 : products (1) have been studied in the temperature range 230-360 K and at total pressure of 1 Torr of helium using the discharge-flow mass spectrometric method. The following Arrhenius expression for the total rate constant was obtained either fr