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Reactions of cis-2,3-Dimethylaziridine, 3-Pyrroline and Pyrrolidine with Me3Al and Me3Ga: Adducts and Dimeric Amides

✍ Scribed by Yuankui Zhang; Peter H. M. Budzelaar; Jan M. M. Smits; René de Gelder; Paul R. Hageman; Anton W. Gal

Book ID
102167397
Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
192 KB
Volume
2003
Category
Article
ISSN
1434-1948

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## Abstract The Staudinger reactions of SP(N~3~)~3~ (1) with 1, 2 and 3 equiv. of triphenylphosphane PPh~3~ and (TMS)~2~N–(TMS)N–PPh~2~ (2) have been investigated (TMS = Me~3~Si). Reaction with PPh~3~ yields the single and double Staudinger products SP(N~3~)~2~NPPh~3~ (3) and SP(N~3~)(NPPh~3~)~2~ (