Reactions of Charged Substrates. 4. The Gas-Phase Dissociation of (4-Substituted benzyl)dimethylsulfoniums and -pyridiniums
โ Scribed by Buckley, Neil; Maltby, David; Burlingame, Alma L.; Oppenheimer, Norman J.
- Book ID
- 115491145
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 380 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Gas-phase eliminations of 4-substituted-2-alkoxythiazoline-5-ones have been studied. These compounds eliminate via a six-membered transition state to produce 4-substituted-thiazolidine-2,5-diones. These eliminations are unimolecular first-order reactions. Utilization of this thermolysis reaction
## Abstract Collisional activation of protonated 2โ, 3โ and 4โiodoanilines in a dualโcell Fourier transform ion cyclotron resonance spectrometer results in the loss of an iodine atom to yield product ions of __m__/__z__ 93. Ionโmolecule reactions and energyโresolved collisionโactivated dissociation
Gas-phase nucleophilic substitution reactions of Y-benzyl chlorides with X-phenoxide and Xthiophenoxide nucleophiles were investigated theoretically using the PM3 semi-empirical MO method. The Leffler-Grunwald rate-equilibrium and Brรธnsted correlations predict that the degree of bond formation in th