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Reactions of cationic iron P-coordinated (diphenylphosphino) alkynes with dicobalt octacarbonyl

โœ Scribed by Elmostafa Louattani; Joan Suades; Angel Alvarez-Larena; Joan F. Piniella; Gabriel Germain


Book ID
103227699
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
474 KB
Volume
506
Category
Article
ISSN
0022-328X

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Reactions of platinum ฯƒ-acetylide comple
โœ Jack Lewis; Bing Lin; Paul R. Raithby ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Springer ๐ŸŒ English โš– 482 KB

Treatment of platinum ~-acetylide complexes trans-Pt(PR3)/(C~CC~CR')2 (1) with two equivalents of Co2(CO)8 gave complexes trans-Pt( PR3 3) and ( 4), where R = Et or n-Bu and R' = H or SiMe 3, in high yields. The unsubstituted platinum-alkyne-cobalt complex (i.e. R'= H) reacted with alkenes (norborny