Reactions of (Carbonylimido)sulfur(IV) Derivatives with TAS-Fluoride, (Me 2 N) 3 S + Me 3 SiF 2-

On the Staudinger Reaction of SP(N3)3 wi

On the Staudinger Reaction of SP(N3)3 with PPh3 and(Me3Si)2N–(Me3Si)N–PPh2

✍ Nadine Götz; Sebastian Herler; Peter Mayer; Axel Schulz; Alexander Villinger; Ja 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 187 KB

## Abstract The Staudinger reactions of SP(N~3~)~3~ (1) with 1, 2 and 3 equiv. of triphenylphosphane PPh~3~ and (TMS)~2~N–(TMS)N–PPh~2~ (2) have been investigated (TMS = Me~3~Si). Reaction with PPh~3~ yields the single and double Staudinger products SP(N~3~)~2~NPPh~3~ (3) and SP(N~3~)(NPPh~3~)~2~ (

Conversion of Alkyltantalum Chlorides to

Conversion of Alkyltantalum Chlorides to Fluorides Using Trimethyltin Fluoride as a Fluorinating Agent. Crystal Structures of ( p -MeC 6 H 4 CH 2 ) 3 TaF 2 , (Me 3 SnCl·Me 3 SnF·TaF 5 ) n , (Me 3 Si) 2 CHTaCl 4 , {(Me 3 Si) 2 CHTaCl 4 ·[(Me 3 Si) 2 CH] 2 Ta 2 Cl 6 (μ 2 -O)}, and (Me 3 Si) 2 CHTaF 4†

✍ Guzyr, Olexandr I.; Schormann, Mark; Schimkowiak, Jürgen; Roesky, Herbert W.; Le 📂 Article 📅 1999 🏛 American Chemical Society 🌐 English ⚖ 129 KB

Cyclopentadiene Elimination Reactions fo

Cyclopentadiene Elimination Reactions for the Preparation of Organoindium(III) Derivatives. Crystal and Molecular Structures of Me 2 In(acac), (Me 3 CCH 2 ) 2 In(acac), (Me)(Me 3 CCH 2 )In(acac), and [Me 2 InNH(t-Bu)] 2

✍ Beachley,, O. T.; MacRae, David J.; Churchill, Melvyn Rowen; Kovalevsky, Andrey 📂 Article 📅 2003 🏛 American Chemical Society 🌐 English ⚖ 171 KB

Cyclopentadiene Elimination Reactions fo

Cyclopentadiene Elimination Reactions for the Preparation of Organoindium(III) Derivatives. Crystal and Molecular Structures of Me 2 In(acac), (Me 3 CCH 2 ) 2 In(acac), (Me)(Me 3 CCH 2 )In(acac), and [Me 2 InNH(t-Bu)] 2

✍ Beachley,, O. T.; MacRae, David J.; Churchill, Melvyn Rowen; Kovalevsky, Andrey 📂 Article 📅 2003 🏛 American Chemical Society 🌐 English ⚖ 9 KB

Reactions of (Me2N)xCl3−xP = S (x = 1, 2

Reactions of (Me2N)xCl3−xP = S (x = 1, 2 and 3) with metal halides

✍ S.R. Wade; G.R. Willey 📂 Article 📅 1981 🏛 Elsevier Science ⚖ 301 KB

Synthesis and Spectroscopic Characteriza

Synthesis and Spectroscopic Characterization of Pyrrolidyl and Piperidyl Dithioformate Derivatives of Dimethyltellurium(IV) Compounds. Crystal Structures of Me 2 Te[S 2 CN(CH 2 ) 3 CH 2 ] 2 , Me 2 Te[S 2 CN(CH 2 ) 4 CH 2 ] 2 , Me 2 Te{[S 2 CN(CH 2 ) 3 CH 2 ][S 2 CN(CH 2 ) 4 CH 2 ]}, Me 2 TeCl[S 2 CN(CH 2 ) 3 CH 2 ], Me 2 TeBr[S 2 CN(CH 2 ) 3 CH 2 ], Me 2 TeI[S 2 CN(CH 2 ) 3 CH 2 ], Me 2 TeCl[S 2 CN(CH 2 ) 4

✍ Drake, John E.; Yang, Jincai 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 354 KB