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Conversion of Alkyltantalum Chlorides to Fluorides Using Trimethyltin Fluoride as a Fluorinating Agent. Crystal Structures of ( p -MeC 6 H 4 CH 2 ) 3 TaF 2 , (Me 3 SnCl·Me 3 SnF·TaF 5 ) n , (Me 3 Si) 2 CHTaCl 4 , {(Me 3 Si) 2 CHTaCl 4 ·[(Me 3 Si) 2 CH] 2 Ta 2 Cl 6 (μ 2 -O)}, and (Me 3 Si) 2 CHTaF 4†

✍ Scribed by Guzyr, Olexandr I.; Schormann, Mark; Schimkowiak, Jürgen; Roesky, Herbert W.; Lehmann, Christopher; Walawalkar, Mrinalini G.; Murugavel, Ramaswamy; Schmidt, Hans-Georg; Noltemeyer, Mathias


Book ID
127238298
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
129 KB
Volume
18
Category
Article
ISSN
0276-7333

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Silanediols Derived from Silanetriols. X
✍ Murugavel, Ramaswamy ;Voigt, Andreas ;Chandrasekhar, Vadapalli ;Roesky, Herbert 📂 Article 📅 1996 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 436 KB 👁 2 views

The silanediols RN(SiMe3)Si(OSiMe3)(0H)2 (R = 2,4,6-were characterized by means of mass, IR and NMR (lH and Me3C6H2 4, 2,6-Me2C6H3 5 , and 2,6-iPr2C6H3 6) were prepa-2gSi) spectroscopy. Additionally, the molecular structures of red by the reactions of the respective silanetriols RN(SiMe3)-4 and 7 we