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Reactions of carbonyl diisocyanate with amides and acids

โœ Scribed by Akteries, Bernhard ;Jochims, Johannes C.

Publisher
Wiley (John Wiley & Sons)
Year
1986
Tongue
English
Weight
763 KB
Volume
119
Category
Article
ISSN
0009-2940

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The reactivity of the aziridinium cation towards the hydroxyl group of alcohols and phenols makes possible a simple synthesis of 2-alkoxyethylamines 111. If the reaction is carried out with a-hydroxy esters ( I ) and aziridinium tetrafluoroborate (2), one obtains first the salts (3) and then, by lo