Carbonyl diisocyanate: A new preparation and some reactions
β Scribed by Akteries, Bernhard ;Jochims, Johannes C.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1986
- Tongue
- English
- Weight
- 678 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0009-2940
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## Abstract The carboxamides RCONH~2~ [Rο£ΎPh (1), __t__Bu (2)] react with BEt~3~ and with (9Hβ9βBBN)~2~ to give the (acylamino)diethylboranes 3, 4 and the 9βacylaminoβ9βBBN 5, 6, respectively. Compounds 3 and 4 are largely monomeric (NMR) in solution and dimeric as crystalline solids [Xβray structur
## Abstract Reaction of dithioic acids with dicyclohexylcarbodiimide has been found to give the corresponding bis(thioacyl) sulfides **1** in good yield, which are very useful thioacylating reagents under mild reaction conditions. Most of the aromatic thioanhydrides (**1**, R = aromatic) are fairly