Reactions of carbon monosulphide. An experimental kinetic technique and a study of the reaction of CS with O2
β Scribed by W.H. Breckenridge; W.S. Kolln; D.S. Moore
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 695 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
A'flow-tube technique has Seen developed for studying the kinetics of elementary reactions of gaseous monomeric. CS. CYbon.monosulphide is generated by means of a low-power electrcddkless discharge in a dilute CSz/Ar stream, fo which reactive gazes may be added through a moveable injector. Detection of CS at pressuies of.less than 2 X lo4 ton . is'achieved using multi-path ultraviolet absorp~on. The reaction of CS with 02 has been shoti to be very slow in the --ieniperature range 300 E to 670 K.
', 1. htroduction . .
π SIMILAR VOLUMES
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The relative rate technique has been used to investigate the kinetics of the reaction of Cl atoms with carbon disultide, CS,, at 700 Torr total pressure of air at 298 K. The decay rate of CSz was measured relative to CHI, CH,CI and CHFQ For experiments using CH4 and CHFI references, the decay rate o
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