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Reactions of [(C5Me5)ZrF3] with AlMe3–Synthesis and Structure of a Zirconium–Aluminum–Carbon Cluster

✍ Scribed by Dipl.-Chem. Axel Herzog; Prof. Dr. Herbert W. Roesky; Dr. Zdirad Zak; Dr. Mathias Noltemeyer


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
241 KB
Volume
33
Category
Article
ISSN
0044-8249

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The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th