Reactions of C2(a 3πu) with CH4, C2H2, C2H4, C2H6, and O2 using multiphoton UV excimer laser photolysis
✍ Scribed by V.M. Donnelly; Louise Pasternack
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 572 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The successive C-H bond dissociation energies of CH,, &Hz. C2H4, and H&O (ketene) are determined using large basis sets and a high level of correlation treatment. For CHI, C2H2, and C2H4 the computed values are in excellent agreement with experiment. Using our results we recommend 107.9 +2.0 and 96.
Study of n-butane pyrolysis at high temperature in a flow system allows measurement of the sum of the rate constants of the initiation reactions (2) and of the Arrhenius parameters of the reactions Established data for kl/k2 allow estimation of kl for 951'K and this, with recent thermochemical da