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Reactions of bis[bis(trimethylsilyl)methyl]germylene and the corresponding stannylene with diazidosilanes

✍ Scribed by Toshiyuki Ohtaki; Yoshio Kabe; Wataru Ando

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
682 KB
Volume
5
Category
Article
ISSN
1042-7163

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✦ Synopsis

The reactions of bis[bis(trimethyIsilyl)methyl]germylene (1) and the corresponding stannylene (2) with di-tert-butykliazidosilane gave N-(azidosi-1yl)germanimine (4) and the stannanimine (5) in quantitative yields. The structures have been confirmed by single-crystal X-ray diffraction. Crystal data for 4: space group P7, Z e = 2, a = 9.236 ( I ) , b =

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