The reactions of o-, m-and p-benzyne anions and the phenide ion with a series of neutral reagents are described. The m-and p-benzyne anions display similar behavior towards acids, NO and , analogous to that of phenide ion but clearly di β erent from that of o-benzyne anion. The strongly basic and nu
Reactions of benzyne with carbon disulphide in the gas phase
β Scribed by Ellis K. Fields; Seymour Meyerson
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 134 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
These gas phase ion-molecule coupling reactions are analogous to the condensed phase coupling reactions of metallobenzynes with molecules containing multiple bonds.
## Abstract Dialkylaminosilanes react at room temperature with carbon dioxide and with carbon disulphide to give silyl dialkylcarbamates and silyl dialkyldithiocarbamates, respectively. These reactions proceed by an ionic chain mechanism, which requires the presence of catalytic amounts of free ami
Strong infrared chemiluminescence, largely attributable to OCS, was observed in the reactions of 0 atoms with CS, in n fast flow svstem. Vibration&v excited CO was detected only weakly and at IO u