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Coupling reactions of Fe(benzyne)+ and Fe(naphthyne)+ in the gas phase

✍ Scribed by Kan, Steven Z.; Xu, Young C.; Chen, Quan; Freiser, Ben S.

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
467 KB
Volume
32
Category
Article
ISSN
1076-5174

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✦ Synopsis

These gas phase ion-molecule coupling reactions are analogous to the condensed phase coupling reactions of metallobenzynes with molecules containing multiple bonds.

πŸ“œ SIMILAR VOLUMES

Gas-phase reactions of the benzyne negat
Gas-phase reactions of the benzyne negative ions
✍ Wenthold, Paul G.; Hu, Jun; Squires, Robert R. πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 248 KB πŸ‘ 1 views

The reactions of o-, m-and p-benzyne anions and the phenide ion with a series of neutral reagents are described. The m-and p-benzyne anions display similar behavior towards acids, NO and , analogous to that of phenide ion but clearly di †erent from that of o-benzyne anion. The strongly basic and nu

A gas-phase study of ligand effects on t
A gas-phase study of ligand effects on the reactivity of organometallic distonic ion Fe(p-benzyne)+Λ™
✍ Young C. Xu; Quan Chen; Sara K. Poehlein; Ben S. Freiser πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 91 KB πŸ‘ 1 views

This paper reports a gas-phase study of ligand effects on the reactivity of the organometallic distonic ion Fe(p-benzyne) Á . New organometallic distonic ions are generated by introducing a benzene ligand onto the metal center of Fe(p-benzyne) Á . We were interested in whether the reactivity of the