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Reactions of Aroylacetonitriles with Acetoacetates.

✍ Scribed by V. A. Dorokhov; A. V. Vasilyev; S. V. Baranin; O. V. Afanas'ev; A. S. Vorushilov


Book ID
101940639
Publisher
John Wiley and Sons
Year
2003
Weight
97 KB
Volume
34
Category
Article
ISSN
0931-7597

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Penta-O-actyl-l,2-dideoxy-l-nitro-D-gluco-hept-l-enitol reacts with methyl acetoacetate in an unusual Michael reaction, giving the normal adduct (6), and a bicyclic derivative (9) that arises from quasi-dimerization of the former when a high concentration of the base is used. Acetylation of compound