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Reaction of 4-iminothiazolidinone-2 with acetoacetic ester

✍ Scribed by I. D. Komaritsa

Book ID
104783387
Publisher
Springer US
Year
1989
Tongue
English
Weight
245 KB
Volume
25
Category
Article
ISSN
0009-3122

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Penta-O-actyl-l,2-dideoxy-l-nitro-D-gluco-hept-l-enitol reacts with methyl acetoacetate in an unusual Michael reaction, giving the normal adduct (6), and a bicyclic derivative (9) that arises from quasi-dimerization of the former when a high concentration of the base is used. Acetylation of compound