1972: reoe1v.d In UK fw publication 2 Jan-1973) Aromatic radical anions react principally as reducing agent& or nucleophiles la,2 or combinations of these.
Reactions of aromatic radical anions VIII. Organometallic synthesis using sodium naphthalene
β Scribed by Shelton Bank; J.F. Bank
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 126 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
In previous work we have reported that Grignard reagents are readily prepared by magnesium bromide capture of the anion produced from the sodium naphthalene reduction of organic halides.
1 The resultant Grignard can be reacted by conventional reagents including organometallic halides to give other organometallic derivatives
π SIMILAR VOLUMES
In the past few years the high selectivity and yields of radical anion syntheses have found value for the cleavage of tosylates la and sulfonamideslb , preparation of alcoholslc, aminesld, anionsle, olefins'f'g, strained cyclic compoundslh, Grignard reagentsli, organo-