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Reactions of aromatic radical anions VIII. Organometallic synthesis using sodium naphthalene

✍ Scribed by Shelton Bank; J.F. Bank


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
126 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis


In previous work we have reported that Grignard reagents are readily prepared by magnesium bromide capture of the anion produced from the sodium naphthalene reduction of organic halides.

1 The resultant Grignard can be reacted by conventional reagents including organometallic halides to give other organometallic derivatives


πŸ“œ SIMILAR VOLUMES


Reactions of aromatic radical anions. X.
✍ Shelton Bank; Matthew Platz πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 French βš– 183 KB

In the past few years the high selectivity and yields of radical anion syntheses have found value for the cleavage of tosylates la and sulfonamideslb , preparation of alcoholslc, aminesld, anionsle, olefins'f'g, strained cyclic compoundslh, Grignard reagentsli, organo-