## Abstract Reactions of anionic living polymers of styrene, __tert__‐butyl methacrylate, and 2‐(trimethylsiloxy)ethyl methacrylate with perfluoroalkyl (Rf) halides, such as C~4~F~9~(CH~2~)~3~I(1), (CF~3~)~2~CF(CF~2~)~6~I (2), C~4~F~9~(CH~2~)~2~I (3), C~8~F~17~(CH~2~)~2~O(CH~2~)~4~Br (4), were inve
Reactions of anionic living polymers with bromomethyl-functionalized benzoyl peroxides
✍ Scribed by Baki Hazer; Akira Hirao; Cüneyt Volga
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 66 KB
- Volume
- 200
- Category
- Article
- ISSN
- 1022-1352
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Both polystyrenes and polyisoprenes with 1,3-butadienyl end-groups were synthesized by the reactions of polystyryl and polyisoprenyl anions with 6-bromo-3-methylene-1 -hexene (3). The 1,3-butadienyl end-group was further transformed to an anhydride function by Diels-Alder reaction with maleic anhydr
## Abstract Anionic living polystyrene and polyisoprene were allowed to react with six __tert__‐butyl‐dimethylsilyl ethers of ω‐halo‐1‐alkanols 1–6, the trimethylsilyl ether of bromohydrin (7), the __tert__‐butyldimethylsilyl ether of 4‐bromophenol (8), and __tert__‐butyldimethylsilyl 3‐chloropropy