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Reactions of a Trirhenium(III) Neopentoxide Cluster with Ethylene and Alkynes

✍ Scribed by Zhuang, Wei-Wei; Hoffman, David M.


Book ID
126901685
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
311 KB
Volume
16
Category
Article
ISSN
0276-7333

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The reactions of vanadium and cobalt clusters, generated by laser vaporization, with ethylene and acetylene were studied by using a fast flow reactor. In the reaction of small V, with CZH4, the dehydrogenated products V,C,, V&H, were observed. Upon increasing the cluster number, the intensities of t