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Reactions of a gold(i) thiolate complex [Au(Tab)2]2(PF6)2(Tab = 4-(trimethylammonio)benzenethiolate) with diphosphine ligands

✍ Scribed by Zheng, Ai-Xia ;Ren, Zhi-Gang ;Li, Ling-Ling ;Shang, Hai ;Li, Hong-Xi ;Lang, Jian-Ping

Book ID
120763421
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
574 KB
Volume
40
Category
Article
ISSN
1477-9226

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## Abstract The room‐temperature solid‐state reaction of silver acetate with TabHPF~6~ [Tab = 4‐(trimethylammonio)benzenethiolate] followed by recrystallization from MeCN afforded a unique octadecanuclear silver thiolate complex [Ag~9~(Tab)~8~(MeCN)~8~]~2~(PF~6~)~18~Β·4MeCN (1). An X‐ray analysis of