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Reactions of 2-methyleneallyl dianion with aldehydes, ketones, epoxides, and allyl halides

✍ Scribed by Bates, Robert B.; Beavers, William A.; Gordon, Bernard; Mills, Nancy S.

Book ID
120052879
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
558 KB
Volume
44
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Highly Substituted Homoallylvinylcyclopr
Highly Substituted Homoallylvinylcyclopropanes by Indium-Mediated Reaction of Ξ±,Ξ²-Unsaturated Ketones and Aldehydes with Allylic Halides
✍ StephenΒ M. Capps; TimothyΒ P. Clarke; JonathanΒ P.Β H. Charmant; HenningΒ A.Β F. HΓΆpp πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 477 KB πŸ‘ 1 views

Allylindium reagents, prepared from excess allylic halide (Br or I) and indium metal, react with Ξ±,Ξ²-unsaturated ketones and aldehydes to give, after aerobic acidic workup, homoallyl-substituted vinylcyclopropanes. This process was explored and developed after a chance discovery arising from a side