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Reaction of pentaarylantimony with acid halide, aldehyde and ketone

✍ Scribed by Masahiro Fujiwara; Mutsuo Tanaka; Akio Baba; Hisanori Ando; Yoshie Souma


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
382 KB
Volume
508
Category
Article
ISSN
0022-328X

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Highly Substituted Homoallylvinylcyclopr
✍ StephenΒ M. Capps; TimothyΒ P. Clarke; JonathanΒ P.Β H. Charmant; HenningΒ A.Β F. HΓΆpp πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 477 KB πŸ‘ 1 views

Allylindium reagents, prepared from excess allylic halide (Br or I) and indium metal, react with Ξ±,Ξ²-unsaturated ketones and aldehydes to give, after aerobic acidic workup, homoallyl-substituted vinylcyclopropanes. This process was explored and developed after a chance discovery arising from a side