Reactions of (1S,3S)-3-acetoxymethyl-1-(2-acetoxyvinyl)-2,2-dimethylcyclopropane with haloforms under conditions of phase-transfer catalysis
β Scribed by M. A. Klimkin; O. S. Kukovinets; V. G. Kasradze; L. V. Spirikhin; F. Z. Galin
- Book ID
- 110408006
- Publisher
- Springer
- Year
- 2002
- Tongue
- English
- Weight
- 289 KB
- Volume
- 51
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
The Mitsunibu thioesterification was applied to the title 2-amino-l,3propanediol (1). The regio-and stereochemistry of the reaction was investigated in correlation with the nature of substituents attached to the nitrogen.
## Abstract The reaction of 2β(2βmethylaziridinβ1βyl)β3βureidopyridines **12** with triphenylphosphine, carbon tetraβchloride, and triethylamine (Appel's conditions) led to the corresponding carbodiimides **13**, which underwent intramolecular cycloaddition reaction with aziridine under the reactio