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Reactions of (1,5-cyclooctadiene)duroquinonenickel with electron donors

โœ Scribed by A. N. Nesmeyanov; L. S. Isaeva; T. A. Peganova


Book ID
112440317
Publisher
Springer
Year
1975
Tongue
English
Weight
222 KB
Volume
24
Category
Article
ISSN
1573-9171

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Hexachlorocyclopentadiene and 5,5-dimethoxy-l,2,3.4-tetrachlorocyclopenta-2,4-diene react with 1,5-cyclooctadiene to produce a 1:4 syn to anti mixture of diadducts in good yield. The stereochemistry of the diastereomers is examined using X-my and molecular mechanics calculations are used to explore