𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Tandem reverse-electron-demand diels-alder reactions of 1,5-cyclooctadiene.

✍ Scribed by J.Gabriel Garcia; Frank R. Fronczek; Mark L. McLaughlin

Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
274 KB
Volume
32
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Hexachlorocyclopentadiene and 5,5-dimethoxy-l,2,3.4-tetrachlorocyclopenta-2,4-diene react with 1,5-cyclooctadiene to produce a 1:4 syn to anti mixture of diadducts in good yield. The stereochemistry of the diastereomers is examined using X-my and molecular mechanics calculations are used to explore some of the potential causes for the observed diastereoselectivity.

📜 SIMILAR VOLUMES

A tandem decarboxylation and inverse ele
A tandem decarboxylation and inverse electron-demand Diels–Alder reaction of amino-thiophenecarboxylic acids with 1,3,5-triazines
✍ Qun Dang; Edmund Carruli; Feng Tian; Francis W. Dang; Tony Gibson; Wenyu Li; Hua 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 287 KB

The scope of 1,3,5-triazine inverse electron-demand Diels-Alder (IDA) reactions was expanded to include aminothiophenecarboxylic acids as latent dienophiles. A series of 2-amino-3-thiophenecarboxylic acids (1a-d) and a 3-amino-2-thiophenecarboxylic acid (5) were introduced as productive dienophiles

Tandem Inverse Electron Demand Diels—Ald
Tandem Inverse Electron Demand Diels—Alder, Retro-Diels—Alder and Intramolecular Diels—Alder Sequences: One-Pot Synthesis of Diaza-Polycycles.
✍ William J. Bromley; Mairi Gibson; Stuart Lang; Steven A. Raw; Adrian C. Whitwood 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 29 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Ultrasound assisted Diels-Alder reaction
Ultrasound assisted Diels-Alder reactions of 1-azadienes with “normal” electronic demand.
✍ Mercedes Villacampa; Jose' María Pérez; Carmen Avendaño; J.Carlos Menéndez 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 531 KB

Ultrasound irradiaton accelerates hetero Diels-Alder reactions between l-dimethylamino-I-azadienes and electron-defficient dienophiles. Besides the lower reaction times and increased yields, other advantages of the sonicated reactions are the possibility of isolating previously unknown adducts due t