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Reactions of 1,4-enynes with the system CH2I2-Et3Al

✍ Scribed by Ramazanov, I. R.; Yaroslavova, A. V.; Dzhemilev, U. M.; Nefedov, O. M.

Book ID
118809844
Publisher
Springer
Year
2011
Tongue
English
Weight
282 KB
Volume
60
Category
Article
ISSN
1573-9171

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Kinetic studies of the reactions CH2I2 + HI⇄CH3I + I2 and 2 CH3I⇄CH4 + CH2I2 the heat of formation of the iodomethyl radical
✍ Shozo Furuyama; David M. Golden; Sidney W. Benson πŸ“‚ Article πŸ“… 1969 πŸ› John Wiley and Sons 🌐 English βš– 489 KB πŸ‘ 1 views

The rate of the reaction CH212 + H I 2 CH,I + I , has been followed spectrophotometrically from 201 .O to 31 1 .Z0. The rate constant for the reaction I + CH,I, CH,I + I, fits the equation, log (k,/M-'sec-') = 11.45 f 0.18 -(15.11 f 0.44)/0. This value, combined with the assumption that E2 = 0 & 1 k