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Reactions of 1-halocycloheptenes with potassium t-Butoxide and with sodium pyrrolidide

โœ Scribed by A.T. Bottini; K.A. Frost II; B.R. Anderson; V. Dev

Book ID
103398390
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
777 KB
Volume
29
Category
Article
ISSN
0040-4020

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Nucleophilic substitution reactions of t
Nucleophilic substitution reactions of the 2- and 3-halobicyclo[3.2.1]-Oct-2-enes with potassium t-butoxide and with sodium pyrrolidide
โœ A.T. Bottini; Bruce Anderson ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 246 KB

In 1961, Woli.nslryl described the conversion of m-bromocamphene to a mixture of 2-and 3-tbutoxy-k,k3imethylbicyclo[3.2.l]oct-2-ene effected by potassium t-butoxide (z-BuOK), and he rationalized the reaction on the basis of a bicyclo[3.2.l]oct-2-yne intermediate (1) that adds