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Reactions of 1-bromo-2-phenylethane and aluminium bromide: Part I. Isomerisation of 1-bromo-2-phenylethane-1-14C

✍ Scribed by E. H. Adema; F. L. J. Sixma


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
546 KB
Volume
81
Category
Article
ISSN
0165-0513

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Reactions of 1-bromo-2-phenylethane and
✍ E. H. Adema; F. L. J. Sixma πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 442 KB

## Abstract The kinetics of the reaction involving the exchange of bromine atoms between 1‐bromo‐2‐phenylethane‐[^82^Br] and aluminium bromide in carbon disulphide has been studied in the temperature range of βˆ’80Β° to βˆ’100Β°. The energy of activation is 10.6 kcals/mole. The kinetic results can only

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## Abstract 2‐Bromo‐[1‐^14^C]ethanamine hydrobromide (BEA) was synthesized from [2‐^14^C]ethan‐1‐01‐2‐amine hydrochloride, by reaction with HBr in a specially designed chamber at an elevated temperature. The synthetic product was purified in the reaction chamber by fractional vacuum sublimation to

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