The molecular dynamics studies presented m this work are concerned w~th two systems, molten NaCI and CuCI. in the former the iomc radd raUo is 0 74 whde in the latter it is 0 36, which allows the study of the effects due to size difference. Studies of the effects due to charge ordering have also bee
Reactions and Speciation of Technetium and Rhenium in Chloride Melts: A Spectroscopy Study.
β Scribed by Vladimir A. Volkovich; Iain May; John M. Charnock; Bob Lewin
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 65 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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The kinetics of pyridine exchange on truns-[MO,(py),]' have been followed by 'H-NMR in CD,NO, for M = Re, Tc: k298/s-' = (5.5 i 0.1) x 0.04 i 0.02; A H #/kJmol-' = 11 1 f-3, 101 f 9; dSf/JK-'mol-' = +28 \* 10, +68 \* 35. For the ReV complex, pyridine and oxygen exchanges have been measured simultane
Recently, several kinds of alkylbenzenium cations formed in strong acid: have been studied in frozen states by KM7 spectroscopy. l-4) These investigations are very interesting for understanding reaction mechanisms of alkylbenzene. Vie wish to report here some evidence for the presence of p-propylbe