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Reactions and properties of oxo and peroxo derivatives of (pentamethylcyclopentadienyl)-molybdenum and -tungsten

✍ Scribed by J.W. Faller; Yinong Ma

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
799 KB
Volume
368
Category
Article
ISSN
0022-328X

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The synthesis of new nitrido(phthalocyaninato)molybdenum (1-4) and -tungsten complexes (5-7) starting from the corresponding phthalonitriles and MNCl 3 (M = Mo, W) is reported. In addition, the reaction of (tBu 4 Pc)WN ( 6) with PPh 3 leading, after several steps, to the diamagnetic compound