Rate constants for the reactions of OH radicals and C1 atoms with diethyl sulfide (DES), din-propyl sulfide (DPS), and di-n-butyl sulfide (DBS) have been determined at 295 ? 3 K and a total pressure of 1 atm. Hydroxyl radical rate data was obtained using the absolute technique of pulse radiolysis co
✦ LIBER ✦
Reaction Rate Coefficients of OH Radicals and Cl Atoms with Ethyl Propanoate, n -Propyl Propanoate, Methyl 2-Methylpropanoate, and Ethyl n -Butanoate
✍ Scribed by Cometto, Pablo M.; Daële, Véronique; Idir, Mahmoud; Lane, Silvia I.; Mellouki, Abdelwahid
- Book ID
- 127352516
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 320 KB
- Volume
- 113
- Category
- Article
- ISSN
- 1089-5639
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Using relative rate methods, rate constants for the gas-phase reactions of OH radicals and Cl atoms with di-n-propyl ether, di-n-propyl ether-d 14 , di-n-butyl ether and di-nbutyl ether-d 18 have been measured at 296 Ϯ 2 K and atmospheric pressure of air. The rate constants obtained (in cm 3 molecul