๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide, Di-n-propyl sulfide, and Di-n-butyl sulfide

โœ Scribed by Ole J. Nielsen; Howard W. Sidebottom; Linda Nelson; Oliver Rattigan; Jack J. Treacy; Denis J. O'Farrell

Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
577 KB
Volume
22
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

โœฆ Synopsis

Rate constants for the reactions of OH radicals and C1 atoms with diethyl sulfide (DES), din-propyl sulfide (DPS), and di-n-butyl sulfide (DBS) have been determined at 295 ? 3 K and a total pressure of 1 atm. Hydroxyl radical rate data was obtained using the absolute technique of pulse radiolysis combined with kinetic spectroscopy. The chlorine atom rate constants were measured using a conventional photolytic relative rate method. The rate constant for the reaction of C1 atoms with dimethyl sulfide (DMS) was also determined. The following rate constants were obtained:

k(C1 + DES) = (44.1 5 4) X 1 0 . ' ' cm3 molecule-'s-' k(C1 + DPS) = (51.8 5 41 x lo-" cm3 molecuIe-'s-' k(C1 + DBS) = (64.6 5 2) X lo-" cm3 molecule-' s-l

๐Ÿ“œ SIMILAR VOLUMES

Rate constants for the reactions of OH r
Rate constants for the reactions of OH radicals and Cl atoms with Di-n-Propyl ether and Di-n-Butyl ether and their deuterated analogs
โœ Cheryl Harry; Janet Arey; Roger Atkinson ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 144 KB ๐Ÿ‘ 2 views

Using relative rate methods, rate constants for the gas-phase reactions of OH radicals and Cl atoms with di-n-propyl ether, di-n-propyl ether-d 14 , di-n-butyl ether and di-nbutyl ether-d 18 have been measured at 296 ฯฎ 2 K and atmospheric pressure of air. The rate constants obtained (in cm 3 molecul

Rate constants and atmospheric lifetimes
Rate constants and atmospheric lifetimes for the reactions of OH radicals and Cl atoms with haloalkanes
โœ T. Donaghy; I. Shanahan; M. Hande; S. Fitzpatrick ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 616 KB

Rate constants for the reactions of C1 atoms and OH radicals with haloalkanes were measured using the relative rate technique. From these values the atmospheric lifetimes of the organics with respect to C1 atoms and OH radicals were calculated. C1 atoms were produced by the photolysis of chlorine ga

The rate constants for the reaction of t
The rate constants for the reaction of the hydroxyl radical with methyl, n-propyl, and n-butyl nitrites
โœ Donald L. Baulch; Ian M. Campbell; Sandra M. Saunders ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 528 KB

The kinetics of the reaction of OH radicals with methyl, n-propyl, and n-butyl nitrite OH + RON0products have been studied in a discharge flow system under pseudo first-order conditions. The OH radicals were generated by the reaction of H atoms with NO2 and the concentration of OH, monitored by reso

Rate constants for the gas-phase reactio
Rate constants for the gas-phase reactions of OH radicals and Cl atoms with n-alkyl nitrites at atmospheric pressure and 298 K
โœ Ole J. Nielsen; Howard W. Sidebottom; Michael Donlon; Jack Treacy ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 823 KB

## Abstract Rate constants for the reactions of OH radicals and Cl atoms with CH~3~ONO, C~2~H~5~ONO, __n__โ€C~3~H~7~ONO, __n__โ€C~4~H~9~ONO, and __n__โ€C~5~H~11~ONO have been determined at 298 ยฑ 2 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rat