Reaction Rate, Activities, and Affinity
β Scribed by Haase, R.
- Book ID
- 124159122
- Publisher
- Oldenbourg Wissenschaftsverlag
- Year
- 1981
- Tongue
- German
- Weight
- 268 KB
- Volume
- 128
- Category
- Article
- ISSN
- 0942-9352
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π SIMILAR VOLUMES
## Abstract Two published experimental confirmations of either the linear relationship between the reaction rate and its affinity, or the βthermodynamic couplingβ are revised. It is shown that βprovedβ results are more consequences of a given experimental arrangement or of methods used for the trea
In the case of catalytic dehydrogenation of cyclohexane, the linear relation between reaction rate and affinity holds at an appreciable distance away from equilibrium on both sides. In fact, in order to explain this observation, it is necessary to invoke a high value of three for the stoichiometric