Reaction potential map analysis of radical aromatic substitution reactions on substituted benzenes
β Scribed by Satoshi Shimomura; Osamu Kikuchi
- Book ID
- 113256799
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 848 KB
- Volume
- 184
- Category
- Article
- ISSN
- 0166-1280
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π SIMILAR VOLUMES
In previous papers, (2) we reported a novel substitution reaction in which
Benzenesulfonyl radical can be generated from sodium benzenesulfinate in aqueous acetic acid or formic acid. A benzenesulfonyi radical induced radical reaction of tt~-allylsulfonylalkyl substituted aromatic and heteroaromatic derivatives is described. Alkyl radicals can be generated efficiently from
Gencralizcd Hartrce-Fock (CHF) calculations Indicate that the aromatic substitutiou reaction kr the ground state CXI bc classified into three types: (A) nonradical ionic (S N2, SE2) reaction, where the closed-shell character is always retained; (B) electron-transfer type I (ET I) reaction, where the