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Free radical reaction of ω-allylsulfonylalkyl substituted aromatic derivatives

✍ Scribed by Sheow-Fong Wang; Che-Ping Chuang; Wan-Hua Lee

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
647 KB
Volume
55
Category
Article
ISSN
0040-4020

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✦ Synopsis

Benzenesulfonyl radical can be generated from sodium benzenesulfinate in aqueous acetic acid or formic acid. A benzenesulfonyi radical induced radical reaction of tt~-allylsulfonylalkyl substituted aromatic and heteroaromatic derivatives is described. Alkyl radicals can be generated efficiently from allylsulfones. This sulfonyl radical induced reacfon provides a synthetically useful method for the synthesis of polycyclic aromatic and heteroaromatic derivatives.

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