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Reaction Pathway of the Conjugate Addition of Lithium Organocuprate Clusters to Acrolein

โœ Scribed by Nakamura, Eiichi; Mori, Seiji; Morokuma, Keiji


Book ID
126895255
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
789 KB
Volume
119
Category
Article
ISSN
0002-7863

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Mechanism of Remote Conjugate Addition o
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Conjugate addition [1] of a nucleophile to a polyconjugated carbonyl compound is an intriguing reaction as it can potentially result in Cร€C bond formation at one of the remote carbon atoms. In many cases, however, the regioselectivity may be poor, unpredictable, or condition-dependent, and the origi