Reaction of Zirconocene–Carboryne with Alkenes: Synthesis and Structure of Zirconacyclopentanes with a Carborane Auxiliary
✍ Scribed by Ren, Shikuo; Qiu, Zaozao; Xie, Zuowei
- Book ID
- 111904369
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 700 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0276-7333
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📜 SIMILAR VOLUMES
A series of novel azazirconacyclopentenes have been prepared by the thermolysis of diphenylzirconocene in the presence of one equivalent of a wide variety of nitriles. An X-ray crystal structure shows these metallacycles to be dimeric in the solid state. 8.
The reaction of nonconjugated monosubstituted alkenes with t-BuMgCl and Cl2ZrCp2 at room temperature produces the corresponding monoalkylzirconium derivatives in high yields, while conjugated alkenes undergo either a novel t-butylzirconation or hydrozirconation depending on the reaction conditions.