The generation and chemistry of halogenated ketenes has experienced popularity In recent literature (1,2,3). Dlchloroketene reportedly forms the cycloadducts I and II with cyclopentadlene (4) and lndene (5) respectively. Cl Cl a Cl 0 Juts (6) has reported the formation and quinollne-catalyzed lsomer
โฆ LIBER โฆ
Reaction of tropone with mesylsulfene
โ Scribed by J. Ciabattoni; M. Cabell
- Book ID
- 104222866
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 148 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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Photocycloaddition reactions are of special interest from the point of molecular orbital symmetry considerations. 293 Recently we have found that irradiation of tropone in acidic media provided a trans (6+6)X type cycloadd;tion product, dimer I, 4 whereas in neutral media such as in ether it afforde
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