Reaction of tropone with dichloroketene
โ Scribed by J. Ciabattoni; H.W. Anderson
- Book ID
- 104241113
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- French
- Weight
- 197 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
The generation and chemistry of halogenated ketenes has experienced popularity In recent literature (1,2,3). Dlchloroketene reportedly forms the cycloadducts I and II with cyclopentadlene (4) and lndene (5) respectively. Cl Cl a Cl 0 Juts (6) has reported the formation and quinollne-catalyzed lsomerizatlon
๐ SIMILAR VOLUMES
Photocycloaddition reactions are of special interest from the point of molecular orbital symmetry considerations. 293 Recently we have found that irradiation of tropone in acidic media provided a trans (6+6)X type cycloadd;tion product, dimer I, 4 whereas in neutral media such as in ether it afforde