Reaction of trithiazyl trichloride with active methylene compounds
✍ Scribed by Duan, Xiao-Guang; Duan, Xiao-Lan; Rees, Charles W.
- Book ID
- 121414788
- Publisher
- Royal Society of Chemistry
- Year
- 1997
- Weight
- 92 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1472-7781
- DOI
- 10.1039/A703033I
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📜 SIMILAR VOLUMES
Reaction of Trithiazyl Trichloride with Alkenes and Alkynes. -Alkenes and alkynes smoothly react with trithiazyl trichloride to furnish 1,2,5thiadiazoles in one step. 3,4-Dihydrothiadiazoles derived from tetra-substituted alkenes such as (IX) undergo spontaneously ring opening to give readily hydro
## Abstract Benzenamines (1) react with 1,3,5‐trichloro‐1λ^4^,3λ^4^,5λ^4^‐1,3,5,2,4,6‐trithiatriazine (2) to form the novel radicals 2‐(2λ^4^‐2,4,‐dithia‐1,3‐diaza‐2‐chloro‐1,3‐butadien‐1‐yl)‐2λ^4^‐2,1,3‐benzothiadiazol‐1‐yls (4) or 2‐(5‐chlora‐2λ^4^‐2,4‐dithia‐1,3‐diaza‐1,2‐pentadien‐1‐yl)‐2λ^4^‐2