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Reaction of trithiazyl trichloride with active methylene compounds

✍ Scribed by Duan, Xiao-Guang; Duan, Xiao-Lan; Rees, Charles W.


Book ID
121414788
Publisher
Royal Society of Chemistry
Year
1997
Weight
92 KB
Volume
19
Category
Article
ISSN
1472-7781

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Reaction of Trithiazyl Trichloride with Alkenes and Alkynes. -Alkenes and alkynes smoothly react with trithiazyl trichloride to furnish 1,2,5thiadiazoles in one step. 3,4-Dihydrothiadiazoles derived from tetra-substituted alkenes such as (IX) undergo spontaneously ring opening to give readily hydro

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## Abstract Benzenamines (1) react with 1,3,5‐trichloro‐1λ^4^,3λ^4^,5λ^4^‐1,3,5,2,4,6‐trithiatriazine (2) to form the novel radicals 2‐(2λ^4^‐2,4,‐dithia‐1,3‐diaza‐2‐chloro‐1,3‐butadien‐1‐yl)‐2λ^4^‐2,1,3‐benzothiadiazol‐1‐yls (4) or 2‐(5‐chlora‐2λ^4^‐2,4‐dithia‐1,3‐diaza‐1,2‐pentadien‐1‐yl)‐2λ^4^‐2