Reaction of triphenylhydrazine with tert-buttl hydroperoxide
✍ Scribed by Kazuhiro Maruyama; Tetsuo Otsuki
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 132 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Recently the reaction of diphenylpicrylhydrazyl (DFPH) with tert-butyl hydroperoxide has been studied by E.S.R. technique(l) and it was supposed by HGbius and Schneider(2) that DPPH might be decomposed through
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## Abstract tert‐Butylsulfinyl chloride (**1**) reacts smoothly with tert‐butyl hydroperoxide (**2**) in the presence of pyridine to afford a variety of products including pyridinium tert‐butylsulfonate, tert‐butyl tert‐butylthiolsulfonate, tert‐butanol and tert‐butylsulfonyl chloride. The mechanis