Oxidative reactions of nitriles—II : Reactions with tert.-butyl hydroperoxide
✍ Scribed by M.S. Kharasch; George Sosnovsky
- Publisher
- Elsevier Science
- Year
- 1958
- Tongue
- French
- Weight
- 572 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0040-4020
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## Abstract tert‐Butylsulfinyl chloride (**1**) reacts smoothly with tert‐butyl hydroperoxide (**2**) in the presence of pyridine to afford a variety of products including pyridinium tert‐butylsulfonate, tert‐butyl tert‐butylthiolsulfonate, tert‐butanol and tert‐butylsulfonyl chloride. The mechanis